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A series second-first-order mechanism for the oxidation of primary and secondary alcohols by Cr(VI) reagents

✍ Scribed by Seema Agarwal; H.P. Tiwari; J.P. Sharma

Publisher
Elsevier Science
Year
1990
Tongue
French
Weight
561 KB
Volume
46
Category
Article
ISSN
0040-4020

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✦ Synopsis

Based on the experimental data, a definite mechanism for the oxidation of primary and secondary alcohols with PCC and two newly synthesized Cr(V1) reagents has been proposed. The reaction has been shown to be a series reaction rather than a simple one step reaction as reported in the literature. The mechanism proposed has been exemplified by taking 2-pentanol as an example. The kinetic isotope studies have also been performed.

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