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A Series of Lanthanide−Transition Metal Frameworks Based on 1-, 2-, and 3D Metal−Organic Motifs Linked by Different 1D Copper(I) Halide Motifs

✍ Scribed by Cheng, Jian-Wen; Zheng, Shou-Tian; Yang, Guo-Yu


Book ID
111877441
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
583 KB
Volume
46
Category
Article
ISSN
0020-1669

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Construction of 1D and 2D Copper(I) Coor
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## Abstract Treatment of CuI with PhSCH~2~SPh in MeCN solution affords, by a self‐assembly reaction, the monodimensional metal–organic coordination polymer [Cu~4~I~4~{μ‐PhS~2~CH~2~SPh}~2~]__~n~__ (1), in which Cu~4~(μ^3^‐I)~4~ cluster units are linked by the dithioether ligand in a 1D necklace stru