A semiautomatic algorithm for rutherford backscattering analysis
β Scribed by Lawrence R. Doolittle
- Book ID
- 113277692
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 440 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0168-583X
No coin nor oath required. For personal study only.
β¦ Synopsis
Nonlinear
least squares techniques have been applied to Rutherford backscattering spectrometry (RBS). allowing routine n,ultivariable fits of simulated spectra to experimental data. Once a qualitatively correct simulation is made, this algorithm varies p~ameters of the simulation to obtain quantitative results. Optimization is done according to a maximum likelihood cm-squared definition, so that the best fit values of parameters and their uncertainties can be determined. Convergence of the algorithm is rapid fl ,r practical problems, allowing a typical four-variable fit to be accomplished in 30 seconds on a VAX 11/750. This algorithm allows c.mfident treatment of spectra which might otherwise be considered too complex. An implementation of the algorithm is incorporated a, part of an RBS analysis and simulation package, making it readily available for routine RBS analysis.
π SIMILAR VOLUMES
For the first time, Rutherford backscattering spectroscopy (RBS) has been used for in situ monitoring of the electrochemical interface. A thin membrane (d \_ 1.5 c) was used as a window for the electrochemical cell, separating the liquid electrolyte from the vacuum of the beam line. The working elec