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A Self-Assembled, Decameric Water Cluster Stabilized by a Cyano-Bridged Copper(II) Complex

✍ Scribed by Mukhopadhyay, Uday; Bernal, Ivan


Book ID
127268409
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
129 KB
Volume
6
Category
Article
ISSN
1528-7483

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## Abstract The crystal structure of [Cu~2~(cit)(phen)~2~]·6H~2~O (**1**) (citcitrate anion, phen1,10‐phenanthroline) reveals an unusual hydrogen‐bonded water dodecamer. The centrosymmetric dodecamer contains a decameric core with two pensile monomers, which is described as a chair with two handl