Research in the area of molecule-based magnets is rapidly expanding, owing, in part, to numerous breakthroughs in the past decade. [1] The preparation of solid-state architectures of varying dimensionalities from specifically tailored paramagnetic building blocks has proven to be very successful, an
A Self-Assembled 2D Molecule-Based Magnet: The Honeycomb Layered Material {Co3Cl4(H2O)2[Co(Hbbiz)3]2}
✍ Scribed by José Ramón Galán-Mascarós; Kim R. Dunbar
- Publisher
- John Wiley and Sons
- Year
- 2003
- Tongue
- English
- Weight
- 173 KB
- Volume
- 115
- Category
- Article
- ISSN
- 0044-8249
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Octahedro-hexatungsten octadecachloride, W 6 Cl 18 , is soluble in dimethyl sulfoxide (DMSO). Brownish black crystals of W 6 Cl 18 (DMSO) 4 are formed from the brown solution by evaporation of DMSO under dynamic vacuum. The compound crystallizes monoclinically in the space group P2 1 /n (no. 14) wit
The blue mixed-crystal title compound Na 15 [Mo VI 126 Mo V 28 O 462 H 14 (H 2 O) 70 ] 0.5 [Mo VI 124 Mo V 28 O 457 H 14 (H 2 O) 68 ] 0.5 ´ca. 400 H 2 O º Na 15 [1 a] 0.5 [1 b] 0.5 ´ca. 400 H 2 O 1, which crystallizes in the triclinic space group P 1 (a = 30.785(2), b = 32.958(2), c = 47.318(3) A Ê