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A selection method for high performance stationary phases in glass capillary GC. Part 1: The molecular weight distribution of polyglycol phases

✍ Scribed by Vigh, G. Y. ;Bartha, Á. ;Hlavay, J.


Publisher
John Wiley and Sons
Year
1981
Tongue
English
Weight
253 KB
Volume
4
Category
Article
ISSN
0935-6304

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✦ Synopsis


Abstract

The width of the molecular weight distribution (MWD) of polymer stationary phases influences their polarity and other gas chromatographic characteristics. The MWD of the most frequently used polyglycol‐type stationary phases such as Carbowax, Ucon, Emulphor and Pluronic has been determined and compared. The MWD determined by gel chromatography allows for the characterization of the actual batch of a stationary phase, provides a check on its consistency and helps to screen out the apparently less promising phases.