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A Schizophrenic Water-Soluble Diblock Copolymer

✍ Scribed by Shiyong Liu; Norman C. Billingham; Steven P. Armes

Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
105 KB
Volume
113
Category
Article
ISSN
0044-8249

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Two micellar states are possible for a novel PPO-PDEA diblock copolymer synthesized by atom-transfer radical polymerization. Subtle variation of the solution pH value and temperature is all that is needed to form both conventional micelles (with the PDEA block in the core) and reverse micelles (with

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## Abstract A novel tertiary amine and amino acid‐based “schizophrenic” pH‐responsive block copolymer, PDEA‐__b__‐PAP, has been synthesized by RAFT polymerization. By directly dissolving this copolymer in acid or basic aqueous solution block copolymer vesicles with switchable coronas and membranes