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A scalemic synthesis of the scopadulcic acid skeleton. II: Ring-D formation via regiospecific intramolecular aldol and alkylation reactions

โœ Scribed by Jayaram R. Tagat; Mohindar S. Puar; Stuart W. McCombie


Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
212 KB
Volume
37
Category
Article
ISSN
0040-4039

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ChemInform Abstract: A Scalemic Synthesi
โœ J. R. TAGAT; S. W. MCCOMBIE; M. S. PUAR ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 36 KB ๐Ÿ‘ 2 views

Starting with the known ester (I) derived from abietic acid only a trace of the desired title skeleton (XIII) is obtained. It is noteworthy that the aldehyde (VII) under basic or acidic conditions gives exclusively the undesired compound (VIII). -(TAGAT, J.