✦ LIBER ✦

A safe and convenient new procedure for reducing aromatic compounds to birch-type products

✍ Scribed by Robert A. Benkeser; James A. Laugal; Angela Rappa

Book ID: 104233539
Publisher: Elsevier Science
Year: 1984
Tongue: French
Weight: 268 KB
Volume: 25
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)81168-0

No coin nor oath required. For personal study only.

✦ Synopsis

Aromatic compounds can be reduced by a calcium-amine-t-butyl alcohol system to products which are identical to those obtained by a Birch reduction of the same substrates. Recently we' disclosed that aromatic hydrocarbons are reduced by calcium in certain amine solvents to cyclic monoenes.

We now wish to report that by varying reaction conditions, the calcium-amine system can be used to reduce aromatic compounds to products which previously were obtained by Birch-type reductions (Table ).

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