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A ruthenium-catalyzed reconstitutive condensation of acetylenes and allyl alcohols

โœ Scribed by Trost, Barry M.; Dyker, Gerald; Kulawiec, Robert J.

Book ID
126427542
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
357 KB
Volume
112
Category
Article
ISSN
0002-7863

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โœ John C Sworen; James H Pawlow; Will Case; John Lever; Kenneth B Wagener ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 129 KB

Metathesis condensation and isomerization reactions of allylic compounds were examined using Grubbs' second-generation ruthenium catalyst [Ru \* ]. Allyl alcohol and allyl cyanide undergo metathesis condensation releasing ethylene, with conversions being the highest reported for these substrates. Ho