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A route to 3-deoxy-4-O-methyl-D-manno-oct-2-ulosonic acid (4-O-methyl-KDO) and its D-gluco isomer derivatives

✍ Scribed by Zbigniew Pakulski; Aleksander Zamojski

Publisher: Elsevier Science
Year: 1997
Tongue: French
Weight: 377 KB
Volume: 53
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(97)00094-x

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✦ Synopsis

Methoxymercuration of ~ fl-unsaturated ketoester 5 (readily obtained from peracetylated Dgluconic acid 1 via Barton ester) led to a separable mixture of KDO derivative 9 and its D-gluco isomer 10.

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