## Abstract A procedure for the estimation of the mixing time between the last two 90° pulses in the classic three‐pulse sequence NOESY/EXSY is proposed and tested and some considerations for the treatment of the two‐dimensional (2D) ^1^H NMR exchange spectra are given. The rate constants are thus
✦ LIBER ✦
A rigorous statistical analysis of errors incurred in the study of intermolecular fast-exchange equilibria by NMR spectroscopy
✍ Scribed by Milton D Johnston Jr.; Alan P Marchand; A.E Earlywine
- Publisher
- Elsevier Science
- Year
- 1986
- Weight
- 572 KB
- Volume
- 69
- Category
- Article
- ISSN
- 0022-2364
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## Abstract The ^1^H, ^13^C and ^15^N NMR studies have shown that the __E__ and __Z__ isomers of pyrrole‐2‐carbaldehyde oxime adopt preferable conformation with the __syn__ orientation of the oxime group with respect to the pyrrole ring. The __syn__ conformation of __E__ and __Z__ isomers of pyrrol