✦ LIBER ✦

A review of some aspects of electromotive-force measurements for the cells:Pt|H2(g,p°)|H2SO4(aq)|PbO2(s)|PbSO4(s)|Pt, and Pt|H2(g,p°)|H2SO4(aq)|Hg2SO4(s)|Hg(l)|Pt, withp° = 0.1 MPa

✍ Scribed by Joseph A. Rard; Simon L. Clegg

Publisher: Elsevier Science
Year: 1995
Tongue: English
Weight: 742 KB
Volume: 27
Category: Article
ISSN: 0021-9614
DOI: 10.1006/jcht.1995.0009

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✦ Synopsis

published the results of extensive e.m.f. measurements for the activities of H2SO4(aq) from low to high molalities over the temperature range 273.15 K to 333.15 K, using the electrochemical cells: Pt=H2(g, p = 0.101325 MPa)=H2SO4(aq)=PbO2(s)=PbSO4(s)=Pt, and Pt=H2(g, p = 0.101325 MPa)=H2SO4(aq)=Hg2SO4(s)=Hg(l)=Pt.

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The second ionization constant of aqueous sulphuric acid at 298.15 K from the electromotive force of the unbuffered cell: H2(g)/H2SO4(aq)/Hg2SO4(s)/Hg

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