In the electrolysis of pure molten silver nitrate with a silver cathode and a platinum anode at temperatures from 220 to 380°C a reversible cell is formed. When the system is electrolysed for a short time at a steady current density and then the current is interrupted, it tends to reach after a few
A reversible chemical cell of molten potassium nitrate
✍ Scribed by A.J. Arvía; A.J. Calandra; M.E. Martins
- Publisher
- Elsevier Science
- Year
- 1967
- Tongue
- English
- Weight
- 185 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0013-4686
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📜 SIMILAR VOLUMES
The reversible decomposition voltage of sodium nitrate was measured after electrolysis current was switched off in a cell containing the molten salt and platinum electrodes. The residual reversible cell is represented by the following scheme: Na(l)/NaNO,(l)/NO,,O,,Pt. (I) The theoretical standard e
W/~iNW)DW(g), O&9/~. (I) La cellule eat form& par l'6lectrolyse du nitrate de lithium fondu entre des Electrodes de platine. La FFM de la cellule et son coe5cient de temperature sont en bonne concordance avec les r&sultats du calcul thermodynamique base sur des dorm&s thermiques.
## Abutraet-Potentiom titrations of dilute solutions of silver nitrate in molten KNO,-Ba(NO,), with potassium halides have b+n carried out. The solubility products of AgCl, A d solvent at 350" were found to be. ( 7.91 f O-35) x 1O-s, (4023 f O-23) x lo+ an Br and AgI in this (l-964 f O-39) x IO-(m
The electrochemical behaviour of Ni electrodes in a KNO, melt in the 350400°C temperature range has been studied, using the cyclic voltammetry method. The occurrence of an additional anodic double-peak is attributed to some ionic species of nickelite (NiO:-) and nickelate (NiO;) type, of a very diff