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A resonance raman investigation on the CT spectra and photochromism of the binuclear complex (NH3)5RuII(μ-pyrazine)CuII

✍ Scribed by H.E. Toma; P.S. Santos

Book ID
104139095
Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
252 KB
Volume
24
Category
Article
ISSN
0020-1693

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Preparation, spectroscopic properties an
Preparation, spectroscopic properties and resonance Raman excitation profiles of the binuclear complex [{W(CO)5}2μ-pyrazine] and the preresonance Raman spectra of [W(CO)5pyridazine]
✍ H. Daamen; D.J. Stufkens; A. Oskam 📂 Article 📅 1980 🏛 Elsevier Science 🌐 English ⚖ 565 KB

## The binuclear complexes [ {M(C0)5}21.c-pyrazine] (M = 0, W) were readily prepared by heating the mononuclear compounds in an inert atmosphere. The spectroscopic data demonstrate that the M(CO)5 moieties in these complexes have retained C,, symmetry. The two allowed metal to pyrazine CT transition