✦ LIBER ✦

A reply to Skalny's discussion on “Low pressure steam hydration of tricalcium silicate”

✍ Scribed by Vito Alunno-Rossetti; Gerardo Chiocchio; Mario Collepardi

Publisher: Elsevier Science
Year: 1974
Tongue: English
Weight: 249 KB
Volume: 4
Category: Article
ISSN: 0008-8846
DOI: 10.1016/0008-8846(74)90033-7

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✦ Synopsis

In his stimulating discussion (1) of our paper, (2) Dr. Skalny claims that some disagreement exists between our data and those obtained by himself (3)(4)(5) and by other authors. (6'7) We will try to demonstrate that, taking into account the analytical methods available, the results are in good agreement, whereas their interpretation is different.

Three points will be discussed in particular: I) the kinetics of hydration, 2) the surface properties, and 3) the composition of the hydrated products.

Kinetics of hydrat.ion

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C3S samples of different fineness were precured at room temperature and subsequently autoclaved. It was found that, as the fineness is increased: I) the effect of precuring on the hydration rate of C3S in autoclave is less evident; 2) the precuring 754 VoI. 4, No. 5 G. Chiocchio, M. Collepardi

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The authors are very grateful to Chatterji as his remarks provide a welcome opportunity to clarify some points of our paper. According to Chatterji's, in the C3A-gyps~m-water system, we would have attributed "the first part of the second high activity period to ettringite formation." Moreover, Chat