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A Remarkably Long-Lived Benzyl Carbanion

✍ Scribed by Laferrière, Marie; Sanramé, Carlos N.; Scaiano, J. C.


Book ID
125935953
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
81 KB
Volume
6
Category
Article
ISSN
1523-7060

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📜 SIMILAR VOLUMES


Structural features of benzylic carbanio
✍ Kenny B. Lipkowitz; Christopher Uhegbu; Adel M. Naylor; Robert Vance 📂 Article 📅 1985 🏛 John Wiley and Sons 🌐 English ⚖ 807 KB

Benzylic anions were studied with the semiempirical MNDO molecular orbital method. Structural changes were analyzed as metal counterions and solvents were allowed to interact with the benzylic carbon. Generally, benzylic carbanions were found to be trigonal planar but became pyramidal or bent when m

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