## Abstract The reactions of hexachlorocyclotripho‐sphazatriene, N~3~P~3~Cl~6~ (**1**), with 2‐hydroxypyridine (**2**), 2‐aminopyridine (**3**), 2‐amino‐6‐methyl‐pyridine (**4**), and 2‐hydroxy‐4‐methylquinoline (**5**) have been investigated. The products were identified by elemental analyses, IR,
A reinvestigation of the reactions of hexachlorocyclotriphosphazatriene with ethylenediamine and ethanolamine
✍ Scribed by S.S. Krishnamurthy; K. Ramachandran; A.R. Vasudeva Murthy; Robert A. Shaw; Michael Woods
- Publisher
- Elsevier Science
- Year
- 1977
- Weight
- 148 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0020-1650
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Reactions of hexachlorocyclotriphosphazatriene, N,P,CI, 1, with sodium aryloxides have been studied. Compound 1 was found to react by the nucleophilic substitution pathway to yield monocyclophosphazenes [N,P3Cl,4,6) 5 and N3P3CI4(OC6H2 Me-4-Bui-2,6), 61 and bi(cyc1ophosphazenes) Phosphorus-Nitrogen
Measurements of the rates of homogeneous reactlon of mono-, dl-and tn-ethanolamme by various workers are cntmslly compared Some dlscrepancles remam unexplamed but It seems probable that a zwltterlon IS the mtermedlate m the formatlon of carbamate and that the reactlon of DEA (but not of MEA) LS cata