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A reinvestigation of the mass spectra of zinc acetate and cobalt acetate

✍ Scribed by DiDonato, G. C.; Busch, K. L.

Book ID
120836732
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
819 KB
Volume
25
Category
Article
ISSN
0020-1669

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The electron impact mass spectra of the acetates of zinc, magnesium, cobalt and manganese have been investigated using a direct inlet probe. Volatile tetrahedral complexes are produced on heating, and ions of the form [~(OC0CH3),O]" (M = CO and Mu) and [N4(OCOCH3),0]+ (N = Zn or Mg) are observed. A

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Vibrational spectra of carboxylato complexesβ€”I. Infrared and Raman spectra of beryllium(II) acetate and formate and of zinc(II) acetate and zinc(II) acetate dihydrate
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The spectra of the title compounds have been recorded and interpreted. On this basis, the structures of the anhydrous compounds Be(OOCH)\*, Be(OOCMe),, Zn(OOCMe), are predicted to have tetrahedral coordination with the carboxylate ions acting as bidentate ligands.