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A reinvestigation of the CBr+ chemiluminescence in a helium afterglow

✍ Scribed by Masaharu Tsuji; Robert Kuhn; John P. Maier; Satoru Nishitani; Keiji Shinohara; Hiroshi Obase; Yukio Nishimura

Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
245 KB
Volume
119
Category
Article
ISSN
0009-2614

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✦ Synopsis

The emission spectrum produced from the flowing He afterglow reaction of CBr 4 has been re-examined. The a 31I 0 ~ ~ X 1~ + emission subsystem of CBr + is identified in addition to the a3IIl-; X 1~1+ subsystem reported previously. The vibrational constants of the a3EIo + substate are estimated to be (in cm 1) T~ = 22449+_2, w e -906+2, o~ex e = 7.8_+0.3, and the a3IIr state spin-orbit splitting constant of CBr + is 369+ 8 cm -1. A new ultraviolet emission system (2650 2900 ~.) is tentatively assigned to the AIII ~ X ix+ transition of CBr +.

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