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A reinvestigation of asymmetric induction in diels-alder reactions to chiral acrylates.

✍ Scribed by Wolfgang Oppolzer; Mark Kurth; Daniel Reichlin; Frank Moffatt


Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
214 KB
Volume
22
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES


Asymmetric induction in Diels-Alder reac
✍ Wolfgang Oppolzer; Mark Kurth; Daniel Reichlin; Christian Chapuis; Martin Mohnha πŸ“‚ Article πŸ“… 1981 πŸ› John Wiley and Sons 🌐 German βš– 328 KB

## Abstract Starting from the enantiomerically pure monoterpenes (+)‐pulegone (**3**), (+)‐limonene (**7**), (βˆ’)‐β‐pinene (**9**), (+)‐ and (βˆ’)‐camphor (**13**) or (+)‐cholestenone (**11**) the chiral alcohols **4, 5, 6, 8, 10, 12, 14, 15, 16, 17** et **18** were prepared; their acrylates **II** un

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High asymmetric induction in diels-alder
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Starting from (R)-(+)-and from (S)-(-)-camphor the chiral alcohols 1: 2 and 3 have been prepared; their acrylates II underwent TiCl,(OR),-promoted Diels-Alder additTons to cyclopentadiene giving efficiently in a predictable manner either the (2R)-or the (2S)-adducts III with up to virtually quantita

Asymmetric induction in Diels-Alder reac
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Asymmetric inductive effects have been measured on the Diels-Alder reaction of dimethyl fumarate with o-quinodimethane bearing a chiral u-alkoxy group. The chiral substituents used were f-phenylethoxy, 2-(1-phenyl)propoxy, 1-(2\_phenyl)propoxy, 2-(4-phenyljbutoxy and l-cyclohexylethoxy. The greatest