## Abstract Starting from the enantiomerically pure monoterpenes (+)βpulegone (**3**), (+)βlimonene (**7**), (β)βΞ²βpinene (**9**), (+)β and (β)βcamphor (**13**) or (+)βcholestenone (**11**) the chiral alcohols **4, 5, 6, 8, 10, 12, 14, 15, 16, 17** et **18** were prepared; their acrylates **II** un
A reinvestigation of asymmetric induction in diels-alder reactions to chiral acrylates.
β Scribed by Wolfgang Oppolzer; Mark Kurth; Daniel Reichlin; Frank Moffatt
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- French
- Weight
- 214 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0040-4039
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
Starting from (R)-(+)-and from (S)-(-)-camphor the chiral alcohols 1: 2 and 3 have been prepared; their acrylates II underwent TiCl,(OR),-promoted Diels-Alder additTons to cyclopentadiene giving efficiently in a predictable manner either the (2R)-or the (2S)-adducts III with up to virtually quantita
Asymmetric inductive effects have been measured on the Diels-Alder reaction of dimethyl fumarate with o-quinodimethane bearing a chiral u-alkoxy group. The chiral substituents used were f-phenylethoxy, 2-(1-phenyl)propoxy, 1-(2\_phenyl)propoxy, 2-(4-phenyljbutoxy and l-cyclohexylethoxy. The greatest