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A Reference Electrode System for Electrochemical Measurements in Pure Water

โœ Scribed by Hongliang Huang; Qiang Wang; Chuan-Sin Cha; Juntao Lu; Lin Zhuang


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
303 KB
Volume
23
Category
Article
ISSN
1040-0397

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## Abstract We report a reference electrode for direct use in tetrahydrofuran (THF) at low temperatures. A reference solution containing equimolar amounts of ferrocene/ferrocenium hexafluorophosphate (Fc/Fc^+^) are prepared to give a 4โ€…mM solution in THF that contains tetrabutylammonium hexafluorop

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## Abstract The appearent firstโ€order rate constants for the oxidation of water by iron tris (bipyridyl) (Fe (bpy)^3+^~3~), and reduction of water by methylviologen (MV^+^) catalyzed by a stabilized RuO~2~ or Ptโ€sol, respectively, were measured. Rate constants for water oxidation at pH 7 of 0.4 s^โˆ’