A reapraisal of the reaction of quinones with hydrazoic acid
β Scribed by G.R. Bedford; G. Jones; B.R. Webster
- Publisher
- Elsevier Science
- Year
- 1966
- Tongue
- French
- Weight
- 191 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
The Schmidt reaction, using concentrated sulphurio acid and hydrasoic acid at O*, as applied to alkyl substituted quinones has been the subject of recent studies (1), Folkers & a. come to the conclusion that in the case of quinones such aa h and Ib the products are exclusively of type IIa and IIb.
π SIMILAR VOLUMES
The reaction of BfoH12(SMe2)2 (1) with HN3 yields arachno-BfoHf AN3)(NH2) (2), a product with a p N H 2 group. Compound 2 can be hydrolysed to give the known arachno-B9Hf3(NH3) (3). nido-NB9Hf ,(N3) (4) is formed from 2 by a deprotonationlprotonation sequence. The azaborane nido-NBfd13 (5) is a prod