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A reaction of 6-bromo-1,2-naphthoquinone with tri(n-butyl)phosphine: A convenient route to phosphorus-containing 1,2-naphthoquinones and 1,2-dihydroxynaphthalenes

✍ Scribed by A. V. Bogdanov; V. F. Mironov; N. R. Khasiyatullina; A. I. Konovalov


Book ID
106520433
Publisher
Springer
Year
2007
Tongue
English
Weight
251 KB
Volume
56
Category
Article
ISSN
1573-9171

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The first examples of a Lewis acid catalysed [2+2]cycloaddition between styrenes and naphthoquinones have been observed. The reactions of both methoxyl and acetoxylnaphthoquinones were both regio-and stereospecific. When m-methoxystyrene was employed a novel tetracycle was also formed, and by an une