Kinetic isotopic effects (KIE) were measured for oxidation, bromination and selenylation of c-C6Ht2/c-C&i2 in pyridine solution for different Gif-type, Fenton and other systems. The comparison of KIE and relative reactivity data for the pair c-C5Ht&C6Ht2 proved that the mechanism of activatton in Gi
A reaction kinetic study on the Gif-type biomimetic oxidation of cyclohexane
โ Scribed by Seong-Bo Kim; Kyu-Wan Lee
- Book ID
- 110642089
- Publisher
- Springer US
- Year
- 1995
- Tongue
- English
- Weight
- 456 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0256-1115
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๐ SIMILAR VOLUMES
The kinetics of ethane oxidation was studied a t 320,340,353 and 38OoC, mixture composition 2 C ~H G + 1 02. and total pressure 609 torr. I t was found that a t 320ยฐC CH20 and CH3CHO were branching agents. A series of experiments was conducted on 2C2Hfi + 0 2 oxidation in the presence of 0.7% 14C-la
this work an investigation of the hydrogen oxidation reaction at platinum and at platinum/polymer electrolyte interfaces in contact with aqueous solutions composed of mixtures of HzS04 and KzS04 (pH range of 0.2-7.5) was carried out. The studies were conducted using cyclic voltammetry, rotating disk