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A rare Cu(I)/Cu(II)-azide complex showing honeycomb-type net structure: Synthesis, structure, and magnetic studies

โœ Scribed by Yu-ting Yang; Feng Luo; Yun-xia Che; Ji-min Zheng


Book ID
103838198
Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
580 KB
Volume
888
Category
Article
ISSN
0022-2860

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A Series of Trinuclear Cu II Ln III Cu I
โœ Shiga, Takuya; Ohba, Masaaki; ลŒkawa, Hisashi ๐Ÿ“‚ Article ๐Ÿ“… 2004 ๐Ÿ› American Chemical Society ๐ŸŒ English โš– 355 KB

A series of trinuclear Cu(II)Ln(III)Cu(II) complexes with the bridging ligand 2,6-di(acetoacetyl)pyridine have been prepared by one-pot reaction with Cu(NO(3))(2).3H(2)O and Ln(NO(3))(3).nH(2)O in methanol. X-ray crystallographic studies for all the complexes indicate that two L(2)(-) ligands select