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A Rapid Catalytic Preparation of Sodamide in Liquid Ammonia and Some of its Uses in the Preparation of Acetylenic Materials

✍ Scribed by Vaughn, Thomas H.; Vogt, R. R.; Nieuwland, J. A.


Book ID
127286283
Publisher
American Chemical Society
Year
1934
Tongue
English
Weight
318 KB
Volume
56
Category
Article
ISSN
0002-7863

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A new convenient preparation of samarium dibromide in THF is reported. Pinacol coupling reactions using SmBr 2 in catalytic amounts together with mischmetall as a coreductant have been performed with a variety of carbonyl compounds.