A radiochemical method for measuring radical yields in the radiolysis of liquid hydrocarbons
β Scribed by R.A. Holroyd; G.W. Klein
- Publisher
- Elsevier Science
- Year
- 1962
- Weight
- 631 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0020-708X
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π SIMILAR VOLUMES
Tl~e primary radicals produced during radiolysis of methanol have been delcctcd by a spin trapping method. The electron spin resonnnce spectra b'xre directly observed during radiolysis of r-BuWO solutions wirh a 3 hlcV electron beam from an accclcrator. 7l1csc showed thal mcthoxy, CHaOg, and hydrow
The rate coefficient for an alkyl peroxy (RO2)-~ alkyl hydroperoxy radical isomerisation reaction has been measured directly for the first time (with R = neo-pentyl). The alkyl radical was generated by the 248 nm pulsed photolysis of neo-pentyl iodide and the OH product of the peroxy radical reactio