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A Radical Chain Mechanism Coupled to Autocatalysis. The Oxidation of N , N -Dimethyl- p -phenylenediamine by Peroxodisulfate

โœ Scribed by Nickel, Ulrich; Peris, Carlos Vivas; Ramminger, Ute


Book ID
121402564
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
211 KB
Volume
106
Category
Article
ISSN
1089-5639

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A spectrophotometrlc flow-mJect]on method was developed for the determmatlon of subnanogram amounts of manganese@) based on Its catalytic effect on the oxldatlve couphng of N,N-dlmethyl-p-phenylenedlamme with m-phenylenedlamme m the presence of hydrogen peroxIde The catalytic actn@ was greatly enhan