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A Quick Method for the Microanalytical Evaluation of the Dissolving Power of Supercritical Gases

✍ Scribed by Prof. Dr. Egon Stahl; Dipl.-Chem. Winfried Schilz; Dipl.-Chem. Erwin Schütz; Dipl.-Chem. Eberhard Willing

Publisher
John Wiley and Sons
Year
1978
Tongue
English
Weight
714 KB
Volume
17
Category
Article
ISSN
0044-8249

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✦ Synopsis

Abstract

A new method of microextraction with supercritical gases involving direct coupling with thin‐layer chromatography enables the solubility behavior of a large number of natural products to be investigated in pressure gradients of up to 400 bar. The results are summarized in general rules that enable the extractability to be predicted on the basis of the chemical structure. The substances that can be satisfactorily extracted in supercritical carbon dioxide and nitrous oxide are preferably lipophilic. The extracting capacity of the two gases was compared using alkaloids. In the case of polar compounds such as sugars and amino acids the solubility is so low even at pressures of 2500 bar (less than 10 μg/Nl) that application is not practicable. Quantitative tests of the solubility behavior of model substances in supercritical gases provide a basis for the technical application of the method.

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