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A quantum electronic polaron model of the hydrated electron

✍ Scribed by Norah V. Cohan; Mariana Weissmann

Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
368 KB
Volume
22
Category
Article
ISSN
0009-2614

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✦ Synopsis

The ground state energy of the hydrated electron in low temperature ice, AGice, is calculated on the assumption of a quantum electronic polaron model. The Hartree-Fock energy of the bottom of the conduction band, eHF, is estimated from a previous work and the correlation energy, ecorr, is calculated by second order perturbation theory using Toyozawa's interaction hamiltonian. The theoretical value so obtained for AGice = eHF + ecOrr is compared with the experimental results on photoemission into electrolyte solutions.

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