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A quantum chemical investigation of the unimolecular chemistry of the formic acid radical cation and some of its isomers

✍ Scribed by Einar Uggerud; Wolfram Koch; Helmut Schwarz


Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
572 KB
Volume
73
Category
Article
ISSN
0168-1176

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## I989 1,3-hydrogen shifts in both the neutral and ionized states of formic, monothioformic and dithioformic acids are investigated using ab initio molecular-orbital methods. Geometries of stationary points are optimized at the UHF/6-3 1 G\*\* level while relative energies are determined employin