✦ LIBER ✦

A quantitative interpretation of the magnetic field effect on hyperfine-coupling-induced triplet fromation from radical ion pairs

✍ Scribed by A. Weller; F. Nolting; H. Staerk

Publisher: Elsevier Science
Year: 1983
Tongue: English
Weight: 322 KB
Volume: 96
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(83)80109-2

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✦ Synopsis

Lqcrimentaily determined Btt2 x-dues characterizing the magnetic field dependence of molecular triplet production from radiral ion pairs originating from photoinduced electron transfer are compared with semi-empirical values obtained xcordmg to B,,l(hfi) = 2& +Bg)/(B, + Bz) from the root-mean-square values for the hyperfine coupling of the two rddrcals, Bt dnd B2 _ The very good agreement is discussed.

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