Covers the most advanced computational and experimental methods for studying carbon-centered radical intermediates With its focus on the chemistry of carbon-centered radicals and radical cations, this book helps readers fully exploit the synthetic utility of these intermediates in order to prepare
A quantitative assessment of the merostabilization energy of carbon-centered radicals
โ Scribed by Katritzky, Alan R.; Zerner, Michael C.; Karelson, Mati M.
- Book ID
- 115484598
- Publisher
- American Chemical Society
- Year
- 1986
- Tongue
- English
- Weight
- 240 KB
- Volume
- 108
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Covers the most advanced computational and experimental methods for studying carbon-centered radical intermediates With its focus on the chemistry of carbon-centered radicals and radical cations, this book helps readers fully exploit the synthetic utility of these intermediates in order to prepare
## Abstract Review: 49 refs.
The specific rate constants for formation of methyl, aminomethyl, hydroxymethyl and cyanomethyl free radicals were cakulated using the transition state theory. The activation energies were calculated using the UHF in the MNDQ level with complete geometry optimization. Force field calculations were p