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A pulse radiolysis study of I and (SCN) in aqueous solutions over the temperature range 15–90°C

✍ Scribed by Allen John Elliot; Frederick Charles Sopchyshyn

Publisher: John Wiley and Sons
Year: 1984
Tongue: English
Weight: 442 KB
Volume: 16
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550161007

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✦ Synopsis

The extinction coefficients and the decay kinetics of I; and (SCN); have been characterized over the 15-90°C-temperature range. The extinction coefficients of I; at 385 and 725 nm were determined to be 10,000 and 2560M-' cm-', respectively, based on the extinction coefficient of (SCN); at 475 nm being equal to 7600M-' cm-'. At these three wavelengths, all extinction coefficients were constant over the temperature range studied. The rate of decay of both I; and (SCN); was found to be a function of Iand SCN-concentration, respectively, as well as temperature.

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