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A proton NMR investigation of rotation about the C(O)-N bonds of urea

✍ Scribed by Zhao, Yiming; Raymond, Mary Katherine; Tsai, Helen; Roberts, John D.


Book ID
119958191
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
432 KB
Volume
97
Category
Article
ISSN
0022-3654

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## Abstract Rapid __Z__,__E__‐isomerization of nitroenamines Rο£ΏNHο£ΏCHο£ΎC(NO~2~)COOCH~3~ in solutions was investigated by dynamic NMR spectroscopy. In weakly basic solvents all the studied nitroenamines isomerize by a thermal mechanism. In pyridine the isomerization proceeds by the thermal mechanism i