## Abstract In order to corroborate a mechanisms proposed for the fragmentation of the molecular ion of heterosides, involving a hydride migration from the aglycome to the osidic unit, the 4‐[^2^H~2~]‐10‐[^2^H~3~]‐labelled neryl and geranyl‐β‐D‐glucosides 9 and 10 have been synthesised. Deuterated
✦ LIBER ✦
A PROPOSED INVERSION MECHANISM FOR THE FORMATION OF LEVOGLUCOSAN FROM PHENYL β-D-GLUCOSIDE AND TRIMETHYLGLUCOSYLAMMONIUM COMPOUNDS
✍ Scribed by McCLOSKEY, CHESTER M.; COLEMAN, GEORGE H.
- Book ID
- 118168242
- Publisher
- American Chemical Society
- Year
- 1945
- Tongue
- English
- Weight
- 762 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Synthesis of 4- and 10-deuterated neryl
✍
Christian Salles; Jean-Claude Jallageas; Yves Beziat; Henri-Jean Cristau
📂
Article
📅
1992
🏛
John Wiley and Sons
🌐
French
⚖ 593 KB
Investigations in the Biosynthesis of th
✍
Prof. Dr. Lutz F. Tietze; Dr. Holger Geissler
📂
Article
📅
1993
🏛
John Wiley and Sons
🌐
English
⚖ 338 KB
👁 2 views
MI ## M4 Scheme 1 were treated with equal amounts of acetic acid under identical reaction conditions (20 "C, 2 h). The yields of the cyclic tetrapyrroles were determined by HPLC with 5,5,10,10,15,15,20,20-octamethylporphyrinogen as internal The reaction of 2 gave no identifiable products; 3 prov