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A procedure for the oxidation of alcohols to aldehydes based on phase transfer catalysis

โœ Scribed by Derek Pletcher; Stephen J.D. Tait

Publisher
Elsevier Science
Year
1978
Tongue
French
Weight
127 KB
Volume
19
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

A recurring problem in synthesis has been the low selectivity of the methods available for the oxidation of alcohols to aldehydes. As a result a number of sophisticated procedures have been developed (for example those based on dimethylsulphoxidel", chromium trioxide3'4'5 or ruthenium tetroxide6) but none are totally satisfactory. This paper describes a method using potassium dichromate and a phase transfer catalyst which is generally applicable to acid stable alcohols and which is both simple and rapid.

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