A preliminary experimental and theoretical study of the differential capacity — potential curves, especially in low concentrations of electrolytes

✍ Scribed by I.L. Cooper; J.A. Harrison; J. Holloway

• Publisher: Elsevier Science
• Year: 1981
• Tongue: English
• Weight: 665 KB
• Volume: 26
• Category: Article
• ISSN: 0013-4686
• DOI: 10.1016/0013-4686(81)85110-9

✦ Synopsis

AbWact

-Using an automated system designed for making electrode kinetic measurements, differential capacity-potential measurements have been made on mercury and silver over a wide range of electrolyte concentrations and external potentials. We illusirate the necessity for a consistent treatment for the potential drop across the full interfacial region, and propose a new theoretical model which cmphasiscs ion-ion interactions in an interfacial region of reduced Longitudinal relative prmittivity.