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A Predictably Selective Nitration of Olefin with Fe(NO 3 ) 3 and TEMPO

✍ Scribed by Naveen, Togati; Maity, Soham; Sharma, Upendra; Maiti, Debabrata


Book ID
120393292
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
396 KB
Volume
78
Category
Article
ISSN
0022-3263

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The binary system Fe(NO 3 ) 3 -FeBr 3 is a very efficient catalyst for the selective air-oxidation of sulfides to sulfoxides. Since the oxidation is selective, it may be applied to any type of dialkyl and alkyl aryl sulfide, as well as to substrates of biological interest. It develops in mild condit