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A Practical Radical Based Access to Functionalized Geminal Bisphosphonates.

✍ Scribed by Fabien Gagosz; Samir Z. Zard


Publisher
John Wiley and Sons
Year
2003
Weight
13 KB
Volume
34
Category
Article
ISSN
0931-7597

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5-Endo-trig Radical Cyclizations of Bromomethyldimethylsilyl Diisopropylpropargylic Ethers. A Highly Diastereoselective Access to Functionalized Cyclopentanes. -The title ethers (I), (V) and (VIII) undergo a radical-induced 5-exo-dig cyclization-diastereoselective 1,5-hydrogen transfer-5-endo-trig