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A Practical Oxidative Method for the Cleavage of Hydrazide N—N Bonds.

✍ Scribed by Rosario Fernandez; Ana Ferrete; Jose M. Llera; Antonio Magriz; Eloisa Martin-Zamora; Elena Diez; Jose M. Lassaletta

Publisher
John Wiley and Sons
Year
2004
Weight
119 KB
Volume
35
Category
Article
ISSN
0931-7597

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A Practical Oxidative Method for the Cle
A Practical Oxidative Method for the Cleavage of Hydrazide NN Bonds
✍ Rosario Fernández; Ana Ferrete; José M. Llera; Antonio Magriz; Eloísa Martín-Zam 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 225 KB 👁 1 views

The selective N-oxidation of the most nucleophilic amino nitrogen atom in hydrazides is central to the development of an unprecedented methodology for the cleavage of their N[bond]N bonds under oxidative conditions. Treatment of a series of hydrazides 1-9 with peracids such as magnesium monoperoxyph