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A Practical Method for Epoxidation of Terminal Olefins with 30% Hydrogen Peroxide under Halide-Free Conditions

✍ Scribed by Sato, Kazuhiko; Aoki, Masao; Ogawa, Masami; Hashimoto, Tadashi; Noyori, Ryoji


Book ID
111918032
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
60 KB
Volume
61
Category
Article
ISSN
0022-3263

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## Abstract It was found that __tert__‐BuNH~2~ is an efficient catalyst for epoxidation of __Ξ±__,__Ξ²__‐unsaturated ketones with 30% H~2~O~2~ under mild conditions. For most of the cyclic unsaturated ketones used, moderate to excellent yields (45%–93%) were obtained within 24 h period.