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A possible explanation for the anomalous low-pressure activation energy for the decomposition of CO2

✍ Scribed by R.G. Gilbert


Publisher
Elsevier Science
Year
1971
Tongue
English
Weight
329 KB
Volume
11
Category
Article
ISSN
0009-2614

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The potential energy surface for the electronic ground state of CO 2 is refined by means of a two-step variational procedure using the exact rovibrational Hamiltonian in the bond length-bond angle coordinates. In the refinement, the observed rovibrational energy levels for J = 0-4 below 16,000 cm -1