The microwave spectroscopy of \(\mathrm{CH}_{2} \mathrm{DSH}\) and \(\mathrm{CHD}_{2} \mathrm{SH}\) has been revisited with the intent of identifying and assigning transitions in the excited torsional states. This effort has been successful, but in the course of the investigation it has been necessa
A Portion of the Microwave Spectra of CH2DSD and CHD2SD
β Scribed by C.F. Su; M.J. Liu; R. Quade
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 84 KB
- Volume
- 164
- Category
- Article
- ISSN
- 0022-2852
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The microwave torsional-rotational spectra of gauche CH 3 CD 2 OH and CH 3 CD 2 OD have been identified, assigned, and analyzed up to 70 GHz. From the observed a-and c-dipole transitions, it has been possible to determine the effective rotational coefficients and the gauche tunneling energy of the h
The I3C shielding of the isotopomers CH,Cl, CH,DCl, CHD,Cl, and CD,C1 has been calculated for a range of temperatures from an self-consistent field (SCF) shielding surface computed by Buckingham and Olegario. It is found that each successive deuterium substitution increases the shielding by about 0.
The microwave spectrum of the formaldehyde -water complex ( CH 2 O -H 2 O ) has been studied with a pulsedbeam Fourier transform Fabry -Perot cavity spectrometer. Both a-type and b-type transitions were observed for each of the isotopic species studied. To provide additional structural information,