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A polymeric copper(II) complex bridged by benzene-1,3,5-tricarboxyl­ate

✍ Scribed by Wei, Wen-Ying ;Han, Jin-Yu


Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
100 KB
Volume
61
Category
Article
ISSN
1600-5368

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Hydrothermal reaction of 1,3,5-benzenetricarboxylic acid (H 3 btc), 2,2 0 -bipyridine (bipy) and Zn(CH 3 CO 2 ) 2 •2H 2 O gave rise to a threedimensional polymer [Zn 3.5 (m 3 -OH)(btc) 2 (bipy) 2 •H 2 O] n (1). X-ray diffraction analysis reveals that 1 consists of pentanuclear metal clusters and sin