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A picosecond diffuse reflectance laser photolysis study on phenanthrene—pyromellitic dianhydride charge-transfer crystal

✍ Scribed by Norimasa Fukazawa; Hiroshi Fukumura; Hiroshi Masuhara; Jerzy Prochorow


Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
520 KB
Volume
220
Category
Article
ISSN
0009-2614

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✦ Synopsis


Picosecond transient absorption spectra of phenanthrene-pyromellitic dianhydride (PMDA) charge-transfer (CT) crystal were measured for the first time, and the high CT nature of the Sr state was directly confirmed. The formation process of the CT state was completed within a few ps and dependent upon the excitation wavelength. The electronic structure and dynamics were discussed by comparing the results with those of the CT complex in solution.

' A visiting research scholar at the graduate school of the Osaka University (February-March 1993 ) .