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A photoelectron spectral study of the vapour phase tautomerism of 2- and 4-quinolone

✍ Scribed by Pfister-Guillouzo, Genevieve ;Guimon, Claude ;Frank, Judit ;Ellison, Joan ;Katritzky, Alan R.


Publisher
John Wiley and Sons
Year
1981
Tongue
English
Weight
316 KB
Volume
1981
Category
Article
ISSN
0947-3440

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✦ Synopsis


Abstract

PE spectral comparisons of the title compounds with the corresponding O‐ and N‐methyl fixed derivatives show that both 2‐ and 4‐quinolone exist as the NH forms in the vapour phase: none of the OH tautomers could be detected.


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Azaguanine: A Theoretical Study of Its T
✍ J.Guillermo Contreras; Sandra T. Madariaga πŸ“‚ Article πŸ“… 1998 πŸ› Elsevier Science 🌐 English βš– 177 KB

The tautomerism and protonation of 8-azaguanine (azaG) have been studied by means of ab initio methods, both in the gas phase and in aqueous solution. An elimination procedure to choose the most stable tautomeric forms, based on AM1 and HF/6-31G\* energies, has been applied. Tautomers azaG(1,9), aza