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A photochemical reaction involving upper excited states

✍ Scribed by N.C. Yang; Robert L. Loeschen

Publisher
Elsevier Science
Year
1968
Tongue
French
Weight
192 KB
Volume
9
Category
Article
ISSN
0040-4039

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✦ Synopsis

Among various carbcnyl compounds which will undergo photochemical reactions with simple olefins to give oxetanes, 9-anthraldehyde is especially interesting in its behavior.

Although it has a low-lying rr,n+ triplet state, it reacts with simple olefins to form oxetanes in appreciable quantum yields.

πŸ“œ SIMILAR VOLUMES

Comment on β€œGeneralized golden rule trea
Comment on β€œGeneralized golden rule treatment of a photochemical solid-state reaction involving hydrogen tunneling”
✍ B. Prass; D. Stehlik πŸ“‚ Article πŸ“… 1992 πŸ› Elsevier Science 🌐 English βš– 223 KB

The model calculations of the commented paper are based on our experimental reaction rates for the H-transfer in acridinedoped fluorene single crystals. High experimental accuracy (reported one order of magnitude too low) is crucial to realize that precise rates in a specific low-temperature region