A Photochemical Activation Scheme of Inert Dinitrogen by Dinuclear RuII and FeII Complexes
✍ Scribed by Markus Reiher; Barbara Kirchner; Jürg Hutter; Dieter Sellmann; Bernd Artur Hess
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 463 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0947-6539
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📜 SIMILAR VOLUMES
## Abstract [(dppp)~2~Pt~2~H~3~]ClO~4~ [I, dppp = Ph~2~P(CH~2~)~3~PPh~2~] was found to activate the C–S bond and to cause partial hydrogenation of thiophene. Thus, the reaction of I with neat thiophene (T) at reflux temperature yields [(dppp)Pt(SC~4~H~4~‐__C__,__S__)] (II) and [(dppp)~2~Pt~2~(μ‐SC~
## Abstract Mononuclear Fe^IV^ intermediates have been generated in MeOH upon reaction of sodium hypochlorite or hypobromite with a ferrous complex bearing the pentadentate ligands __N__‐methyl‐__N__,__N′__,__N′__‐tris(2‐pyridylmethyl)ethane‐1,2‐diamine (L~5~^2^) or __N__‐methyl‐__N__,__N′__,__N′__